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Section A Atomic structure 1

A1 The nuclear atom 1

A2 Atomic orbitals 5

A3 Many-electron atoms 9

A4 The periodic table 12

A5 Trends in atomic properties 16

Section B Introduction to inorganic substances 21

B1 Electronegativity and bond type 21

B2 Chemical periodicity 25

B3 Stability and reactivity 29

B4 Oxidation and reduction 33

B5 Describing inorganic compounds 37

Section C Structure and bonding in molecules 41

C1 Electron pair bonds 41

C2 Molecular shapes:VSEPR 46

C3 Molecular orbitals:homonuclear diatomics 51

C4 Molecular orbitals:heteronuclear diatomics 56

C5 Molecular orbitals:polyatomics 60

C6 Rings and clusters 65

C7 Bond strengths 69

C8 Lewis acids and bases 73

C9 Molecules in condensed phases 76

Section D Structure and bonding in solids 79

D1 Introduction to solids 79

D2 Element structures 83

D3 Binary compounds:simple structures 87

D4 Binary compounds:factors influencing structure 92

D5 More complex solids 96

D6 Lattice energies 100

D7 Electrical and optical properties of solids 104

Section E Chemistry in solution 109

E1 Solvent types and properties 109

E2 Br？nsted acids and bases 113

E3 Complex formation 117

E4 Solubility of ionic substances 121

E5 Electrode potentials 124

Section F Chemistry of nonmetals 129

F1 Introduction to nonmetals 129

F2 Hydrogen 133

F3 Boron 137

F4 Carbon,silicon and germanium 141

F5 Nitrogen 145

F6 Phosphorus,arsenic and antimony 149

F7 Oxygen 153

F8 Sulfur,selenium and tellurium 157

F9 Halogens 161

F10 Noble gases 165

Section G Non-transition metals 167

G1 Introduction to non-transition metals 167

G2 Group 1:alkali metals 171

G3 Group 2:alkaline earths 175

G4 Group 12:zinc,cadmium and mercury 178

G5 Group 13:aluminum to thallium 181

G6 Group 14:tin and lead 185

Section H Chemistry of transition metals 189

H1 Introduction to transition metals 189

H2 Ligand field theory 193

H3 3d series:aqueous ions 197

H4 3d series:solid compounds 200

H5 4d and 5d series 203

H6 Complexes:structure and isomerism 206

H7 Complexes:kinetics and mechanism 210

H8 Complexes:electronic spectra and magnetism 213

H9 Complexes:π acceptor ligands 217

H10 Organometallic compounds 221

Section I Lanthanides and actinides 227

I1 Lanthanum and the lanthanides 227

I2 Actinium and the actinides 230

Section J Environmental, biological and industrial aspects 235

J1 Origin and abundance of the elements 235

J2 Geochemistry 238

J3 Bioinorganic chemistry 241

J4 Industrial chemistry:bulk inorganic chemicals 246

J5 Industrial chemistry:catalysts 249

J6 Environmental cycling and pollution 253

Further reading 257

Index 259