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Foreword 1

Ⅰ.Heterocyclic Derivatives of Phosphorus 9

Five-Membered Ring Systems Containing Only Carbon and Phosphorus 9

Cyclotetramethylenephosphines 9

Six-Membered Ring Systems Containing Only Carbon and Phosphorus 10

Cyclopentamethylenephosphines 10

1,2,3,4-Tetrahydroisophosphinolines 10

Four-Membered Ring Systems Containing Carbon,Phosphorus,and Oxygen 13

Five-Membered Ring Systems Containing Carbon,Phosphorus,and Nitrogen 14

Five-Membered Ring Systems Containing Carbon,Phosphorus,and Oxygen 17

o-Phenylenechlorophosphonites 17

Six-Membered Ring Systems Containing Carbon,Phosphorus,and Nitrogen 19

Phenphosphazines 19

Six-Membered Ring Systems Containing Carbon,Phosphorus,and Oxygen 21

Salicylchlorophosphonite 21

Ten-Membered Ring Systems Containing Carbon,Phosphorus,and Oxygen 22

Ⅱ.Heterocyclic Derivatives of Arsenic 25

Five-Menmbered Ring Systems Containing Only Carbon and Arsenic 25

Cyelotetramethylenearsines 25

Arsindoles 26

Arsindolines and Isoarsindolines 30

Arsindolines 30

Isearsindolines 31

Arsafluorenes or 2,3-Bcnzarsindoles 36

Six-Mernbered Ring Systems Containing Only Carbon and Arsenic 38

Cyclopentamethylenearsines 38

Tetrahydroarsinolines and Tetrahydroisoarsinolines 42

1,2,3,4-Tetrahydroarsinolines 43

1,2,3,4-Tetrahydroisoarsinolines 45

Arsacridines 49

Arsanthridines 52

2-Arsaperinaphthanes（or 2-Arsaperinaphthindanes） 55

Seven-Membered Ring Systems Containing Only Carbon and Arsenic 57

6-Arsa-1,2,3,4-dibenzcyclohepta-1,3-dienes 57

Five-Membered Ring Systems Containing Carbon, Arsenic, and Oxygen 58

Anhydrides of o-Carboxyphenyl Arsinous and Arsinic Acids 58

o-Phenylenephenylarsonite 62

Spirocyclic Esters of Glycols,o-Dihydroxybenzenes,and α-Hydroxy-carboxylic Acids with Arsonic Acids 62

Tripyrocatechylarsenic Acid 67

Five-Membered Ring Systems Containing Carbon,Arsenic,and Sulfur 70

2-Arsa-1,3-dithiacyclopentanes 70

Five-Membered Ring Systems Containing Carbon,Oxygen,and Two Arsenic Atoms 75

Anhydride of o-Phenylene- bisarsonous Chloride 75

Anhydride of 5,10-Dihydroxy-5,10-dihydroarsanthrene 75

Five-Membered Ring Systems Containing Carbon,Palladium,and Two Arsenic Atoms 77

Six-Membered Ring Systems Containing Carbon, Arsenic, and Nitrogen 80

Phenarsazines 80

Azaphenarsazines 99

Six-Membered Ring Systems Containing Carbon,Arsenic,and Oxygen 100

Phenoxarsines 100

Six-Membered Ring Systems Containing Carbon,Arsenic,and Sulfur 114

Phenyl-thiarsine 114

Phenthiarsine 114

Six-Membered Ring Systems Containing Carbon and Two Arsenic Atoms 116

Ethylene-o-phenylenediarsine 116

Arsanthrene and Its Derivatives 117

Tri-o-phenylenediarsine 125

Seven-Membered Ring Systems Containing Carbon and Two Arsenic Atorns 127

o-Phenylenetrimethylenediarsine 127

Ⅲ.Heterocyclic Derivatives of Antimony 129

Five-Membered Ring Systems Containing Only Carbon and Antimony 129

Cyclotetramethylenestibines 129

Stibinafluorenes 130

Six-Membered Ring Systems Containing Only Carbon and Antimony 134

Cyclopentamethylenestibines 134

Stibacridines 135

Five-Membered Ring Systems Containing Carbon,Antimony,and Oxygen 140

Potassium Antimonyl Tartrate（Tartar Emetic） 140

Derivatives of Pyrocateehol and Other 1,2-Dihydric Phenols 143

Five-Membered Ring Systems Containing Carbon,Antimony,and Sulfur 150

2-Stibina-1,3-dithiacyclopentanes 150

Five-Membered Ring Systems Containing Carbon,Antimony,Oxygen,and Sulfur 151

Antimony Derivatives of Thioglycollic Acid 151

Six-Membered Ring Systems Containing Carbon,Antimony,and Oxygen 152

Phenoxstibines 152

Ⅳ.Heterocyclic Derivatives of Bismuth 157

Six-Membered Ring Systems Containing Only Carbon and Bismuth 157

Cyclopentamethylenebismuthine 157

Five-Membered Ring Systems Containing Carbon,Bismuth,and Oxygen 158

Derivatives of Pyrocatechol and Other 1,2-Dihydric Phenols 158

Ⅴ.Heterocyclic Derivatives of Silicon 161

Six-Membered Ring Systems Containing Only Carbon and Silicon 161

Cyclopentamethylenesilicon Derivatives 161

Index 163